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Study of adsorption-desorption of contaminants on single soil particles using the electrodynamic thermogravimetric analyzer

Journal Article · · Environmental Science and Technology; (USA)
DOI:https://doi.org/10.1021/es00013a010· OSTI ID:6060710
; ;  [1]; ;  [2]
  1. Massachusetts Institute of Technology, Cambridge (USA)
  2. Tufts Univ., Medford, MA (USA)
The isothermal adsorption and desorption of organic vapors on a single soil particle was studied with the aid of the electrodynamic thermogravimetric analyzer (EDTGA). Toluene and carbon tetrachloride were tested at room temperature during their adsorption on Spherocarb, montmorillonite, and Carbopack particles. The maximum amount of either organic compound adsorbed was comparable to that required for one monolayer coverage of the particle surface area. Significant differences among various pairs of solid-organic vapor examined were identified and correlated to differences in solid pore structure and chemical affinity between the organic compound and the solid.
OSTI ID:
6060710
Journal Information:
Environmental Science and Technology; (USA), Journal Name: Environmental Science and Technology; (USA) Vol. 25:1; ISSN ESTHA; ISSN 0013-936X
Country of Publication:
United States
Language:
English