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Kinetics of the catalytic dehydrochlorination of 3,4-dichloro-1-butene by aqueous M/sup +/ hydroxide solutions in the presence of low-molecular-weight alcohols

Journal Article · · Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:6048857
; ;

The dehydrochlorination of 3,4-dichloro-1-butene (3,4-DCB-1) by aqueous solutions of M/sup +/ hydroxides has been studied in the presence of low-molecular-weight alcohols and a quarternary ammonium salt of catamine AB. The effect of the nature of the alcohol and of the alkali metal hydroxide on the efficiency of dehydrochlorination is discussed. The data obtained herein for the relative reactivities of M/sup +/ hydroxides toward dehydrochlorination in aqueous alcohol solutions, as well as the calculations, verify that the dehydrochlorinating agent in these systems is the hydroxide ion.

Research Organization:
V.V. Kuibishev Polytechnical Institute (USSR)
OSTI ID:
6048857
Journal Information:
Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 29:4; ISSN KICAA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALCOHOLS
ALKALI METAL COMPOUNDS
AMINES
AMMONIUM COMPOUNDS
AQUEOUS SOLUTIONS
BUTANOLS
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORINATED ALIPHATIC HYDROCARBONS
DECANOLS
DECHLORINATION
DEHALOGENATION
DEHYDROGENATION
DISPERSIONS
EFFICIENCY
ENERGY
HALOGENATED ALIPHATIC HYDROCARBONS
HETEROGENEOUS CATALYSIS
HEXANOLS
HYDROGEN COMPOUNDS
HYDROXIDES
HYDROXY COMPOUNDS
KINETICS
LITHIUM COMPOUNDS
LITHIUM HYDROXIDES
MIXTURES
MOLECULAR WEIGHT
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
OXYGEN COMPOUNDS
PENTANOLS
POTASSIUM COMPOUNDS
POTASSIUM HYDROXIDES
PROPANOLS
QUATERNARY COMPOUNDS
REACTION KINETICS
SODIUM COMPOUNDS
SODIUM HYDROXIDES
SOLUTIONS
SOLVENT PROPERTIES