Kinetics and mechanism of the dehydrochlorination of 3,4-dichloro-1-butene under phase transfer catalysis conditions
Journal Article
·
· Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:5914666
The aqueous base (hydroxide) dehydrochlorination of halogen-substituted hydrocarbons in the presence of phase transfer catalysts is widely used for the preparation of olefins and dienes. In this paper the aqueous hydroxide dehydrochlorination of 3,4-dichloro-1-butene (3,4-DCB-1) has been studied in the presence of a phase transfer catalyst, catanol. The effect of sodium hydroxide concentration on the nature of the limiting step in this dehydrochlorination reaction has been examined.
- Research Organization:
- V.V. Kuibishev Polytechnical Institute (USSR)
- OSTI ID:
- 5914666
- Journal Information:
- Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 29:4; ISSN KICAA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALKALI METAL COMPOUNDS
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORINATED ALIPHATIC HYDROCARBONS
DECHLORINATION
DEHALOGENATION
DEHYDROGENATION
ENERGY
HALOGENATED ALIPHATIC HYDROCARBONS
HETEROGENEOUS CATALYSIS
HYDROGEN COMPOUNDS
HYDROXIDES
ION EXCHANGE
KINETICS
MATERIALS TESTING
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
OXYGEN COMPOUNDS
QUANTITY RATIO
REACTION KINETICS
SALTING-OUT AGENTS
SODIUM COMPOUNDS
SODIUM HYDROXIDES
TESTING
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALKALI METAL COMPOUNDS
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORINATED ALIPHATIC HYDROCARBONS
DECHLORINATION
DEHALOGENATION
DEHYDROGENATION
ENERGY
HALOGENATED ALIPHATIC HYDROCARBONS
HETEROGENEOUS CATALYSIS
HYDROGEN COMPOUNDS
HYDROXIDES
ION EXCHANGE
KINETICS
MATERIALS TESTING
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
OXYGEN COMPOUNDS
QUANTITY RATIO
REACTION KINETICS
SALTING-OUT AGENTS
SODIUM COMPOUNDS
SODIUM HYDROXIDES
TESTING