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U.S. Department of Energy
Office of Scientific and Technical Information

Recovery of non-ferrous metals from smelter flue dusts and sludges

Patent ·
OSTI ID:6047657
A method is described for treating a smelter by-product so as to recover copper, nickel, zinc, an cobalt metal therefrom and convert any arsenic and sulfur in the smelter by-product into non-leachable forms of arsenic and sulfur, the method comprising: (a) mixing the smelter by-product with hydrated lime to form a paste; (b) forming the paste into agglomerates, (c) roasting the agglomerates in air at a temperature sufficient to oxidize the arsenic and sulfur therein and cause said oxidized arsenic and sulfur to react with the lime in the agglomerates to form non-leachable arsenic-containing and sulfur-containing calcium compounds within the roasted agglomerates; and (d) contacting the roasted agglomerates with a basic aqueous lixiviant solution comprising dissolved ammonia and an ammonium salt so as to dissolve copper, nickel, zinc and cobalt from the roasted agglomerates into the lixiviant solution, thereby converting the lixiviant solution to a pregnant liquor enriched in said copper, nickel, zinc and cobalt.
Assignee:
IMS; EDB-93-120534
Patent Number(s):
A; US 5234669
Application Number:
PPN: US 7-743491
OSTI ID:
6047657
Country of Publication:
United States
Language:
English