Closo-(B/sub 11/H/sub 11/AlCH/sub 3/)/sup 2 -/, an aluminaborane analogue of the closo-(B/sub 12/H/sub 12/)/sup 2 -/ dianion: synthesis, characterization, and molecular structure
Journal Article
·
· Inorg. Chem.; (United States)
A high-yield synthesis of 1-methyl-1-aluminaundecahydrodecaborate(2- dianion), (B/sub 11/H/sub 11/AlCH/sub 3/)/sup 2 -/, an aluminaborane analogue of closo-(B/sub 12/H/sub 12/)/sup 2 -/ dianion is described. The characterization and molecular structure of the dianion is reported. Results of /sup 11/B NMR spectrum of the dianion were used in the characterization process. 7 references, 1 figure.
- Research Organization:
- Ohio State Univ., Columbus (USA)
- OSTI ID:
- 6046920
- Journal Information:
- Inorg. Chem.; (United States), Vol. 27:20
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALKANES
SYNTHESIS
ALUMINIUM COMPOUNDS
ANIONS
BORANES
BORON 11
MOLECULAR STRUCTURE
NMR SPECTRA
BORON COMPOUNDS
BORON ISOTOPES
CHARGED PARTICLES
HYDROCARBONS
IONS
ISOTOPES
LIGHT NUCLEI
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
SPECTRA
STABLE ISOTOPES
400201* - Chemical & Physicochemical Properties
400202 - Isotope Effects
Isotope Exchange
& Isotope Separation
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALKANES
SYNTHESIS
ALUMINIUM COMPOUNDS
ANIONS
BORANES
BORON 11
MOLECULAR STRUCTURE
NMR SPECTRA
BORON COMPOUNDS
BORON ISOTOPES
CHARGED PARTICLES
HYDROCARBONS
IONS
ISOTOPES
LIGHT NUCLEI
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
SPECTRA
STABLE ISOTOPES
400201* - Chemical & Physicochemical Properties
400202 - Isotope Effects
Isotope Exchange
& Isotope Separation