Dichloromethyl alkyl ethers and sulfides in the Reformatskii reaction (in Russian)
Journal Article
·
· J. Org. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:6035945
A study was carried out on the reaction of dichloromethyl alkyl ethers and sulfides with ..cap alpha..-brominated esters in the presence of zinc resulting in the formation of either ..cap alpha..-alkyl-..beta..-alkoxyacrylates (or ..cap alpha..-alkyl-..beta..-alkylthioacrylates) or ..cap alpha..,..cap alpha..,..cap alpha..',..cap alpha..'-tetramethyl-..beta..-alkoxyglutaric acid (or ..cap alpha..,..cap alpha..,..cap alpha..',..cap alpha..'-tetramethyl-..beta..-alkylthioglutaric acid) depending on the structure of the starting bromoester. PMR and IR spectroscopy indicates the geometry of the ..cap alpha..-alkyl-..beta..-alkoxyacrylates and ..cap alpha..-alkyl-..beta..-alkylthioacrylates.
- Research Organization:
- Perm State Univ., USSR
- OSTI ID:
- 6035945
- Journal Information:
- J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 22:4; ISSN JOCYA
- Country of Publication:
- United States
- Language:
- Russian
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ACETONE
ACTIVATION ENERGY
ALKALINE HYDROLYSIS
CARBOXYLIC ACID ESTERS
CATALYTIC EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMICAL SHIFT
CHLORINATED ALIPHATIC HYDROCARBONS
CHLOROFORM
COUPLING
COUPLING CONSTANTS
DECOMPOSITION
DEUTERIUM COMPOUNDS
ELEMENTS
ENERGY
ENERGY LEVELS
ESTERS
ETHERS
EXCITED STATES
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROLYSIS
INFRARED SPECTRA
INTERMEDIATE COUPLING
ISOMERIZATION
J-J COUPLING
KETONES
LYSIS
METALS
MOLECULAR STRUCTURE
NMR SPECTRA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
SOLVOLYSIS
SPECTRA
SYNTHESIS
VIBRATIONAL STATES
YIELDS
ZINC
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ACETONE
ACTIVATION ENERGY
ALKALINE HYDROLYSIS
CARBOXYLIC ACID ESTERS
CATALYTIC EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMICAL SHIFT
CHLORINATED ALIPHATIC HYDROCARBONS
CHLOROFORM
COUPLING
COUPLING CONSTANTS
DECOMPOSITION
DEUTERIUM COMPOUNDS
ELEMENTS
ENERGY
ENERGY LEVELS
ESTERS
ETHERS
EXCITED STATES
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROLYSIS
INFRARED SPECTRA
INTERMEDIATE COUPLING
ISOMERIZATION
J-J COUPLING
KETONES
LYSIS
METALS
MOLECULAR STRUCTURE
NMR SPECTRA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
SOLVOLYSIS
SPECTRA
SYNTHESIS
VIBRATIONAL STATES
YIELDS
ZINC