Reactions of polyhalogeno functional compounds with metals and electrophilic reagents. V. Reaction of trichloroacetophenone with zinc and electrophilic reagents
Journal Article
·
· J. Org. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:7159966
The reaction of trichloroacetophenone with zinc leads to the production of an intermediate ambient organozinc compound, which reacts with acid chlorides, alkylchlorosilanes, and ..cap alpha..-chloro ethers with the preferential formation of O-derivatives of the ..beta..,..beta..-dichloro-..cap alpha..-acyloxy-, ..beta..,..beta..-dichloro-..cap alpha..-trimethylsilyloxy- and ..beta..,..beta..-dichloro-..cap alpha..-alkoxymethoxystyrene type. The PMR spectra were recorded on a Tesla BS-487 instrument at 80 MHz in carbon tetrachloride with TMS as internal standard. The IR spectra were obtained for the individual compounds on a UR-20 spectrophotometer. The Raman spectra were recorded on a DFS-24 spectrometer.
- Research Organization:
- A. M. Gor'kii Perm State Univ. (USSR)
- OSTI ID:
- 7159966
- Journal Information:
- J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 23:5; ISSN JOCYA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACETATES
ACETOPHENONE
ACTIVATION ENERGY
AROMATICS
CARBOXYLIC ACID SALTS
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL SHIFT
COMPLEXES
ELEMENTS
ENERGY
ETHERS
HETEROGENEOUS CATALYSIS
HYDROCHLORIC ACID
HYDROGEN COMPOUNDS
INFRARED SPECTRA
INORGANIC ACIDS
KETONES
METALS
NMR SPECTRA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC SILICON COMPOUNDS
ORGANOMETALLIC COMPOUNDS
RAMAN SPECTRA
REACTION INTERMEDIATES
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
YIELDS
ZINC
ZINC COMPLEXES
400201* -- Chemical & Physicochemical Properties
ACETATES
ACETOPHENONE
ACTIVATION ENERGY
AROMATICS
CARBOXYLIC ACID SALTS
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL SHIFT
COMPLEXES
ELEMENTS
ENERGY
ETHERS
HETEROGENEOUS CATALYSIS
HYDROCHLORIC ACID
HYDROGEN COMPOUNDS
INFRARED SPECTRA
INORGANIC ACIDS
KETONES
METALS
NMR SPECTRA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC SILICON COMPOUNDS
ORGANOMETALLIC COMPOUNDS
RAMAN SPECTRA
REACTION INTERMEDIATES
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
YIELDS
ZINC
ZINC COMPLEXES