Reaction of 1,1-dinitroethane potassium salt with xenon difluoride

Journal Article · Sat May 10 00:00:00 EDT 1986 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6035622

Tselinskii, I V; Mel'nikov, A A; Varyagina, L G; Trubitsin, A E

The potassium salt of 1,1-dinitroethane reacts with xenon difluoride in methylene chloride to form a mixture of products, i.e., acetic acid, 1-fluoro-1,1-dinitroethane, 1-chloro-1,1-dinitroethane, 1,1,1-trinitroethane, and 1,1-dinitroethane. The ratios of the yields depend on the reaction conditions. The proposed mechanism for the formation of the reaction products involves one-electron oxidation of the dinitroethane radical, which enters into reaction with the methylene chloride molecules and intermediate radical particles.

• Research Organization: Lensovet Leningrad Technological Institute, USSR
• OSTI ID: 6035622
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 21:12; ISSN JOCYA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKALI METAL COMPLEXES
ALKANES
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHROMATOGRAPHY
COMPLEXES
ETHANE
FLUORIDES
FLUORINATED ALIPHATIC HYDROCARBONS
FLUORINATION
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HALOGENATION
HYDROCARBONS
KINETICS
METHYLENE CHLORIDE
NITRO COMPOUNDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXIDATION
OXIDIZERS
POTASSIUM COMPLEXES
RARE GAS COMPOUNDS
REACTION INTERMEDIATES
REACTION KINETICS
SEPARATION PROCESSES
SOLVATION
XENON COMPOUNDS
XENON FLUORIDES
YIELDS