Aromatic fluorine derivatives. C. reactions of pentafluorophenol with vanadium, niobium, and antimony fluorides and xenon difluoride

Journal Article · Fri Sep 20 04:00:00 EDT 1985 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5910122

Auramenko, A A; Bardin, V V; Furin, G G; Karelin, A I; Krasil'nikov, V A; Tushin, P P; Yakobson, G G

Pentafluorophenol reacts with vanadium fluorides (VF/sub 5/, VOF/sub 3/, VF/sub 4/) and xenon difluoride giving perfluoro-2,5-cyclohexadien-1-one and the products from dimerization of the pentafluorophenoxyl radical, i.e., perfluoro-6-phenoxy-2,4-cyclo-hexadien-1-one, perfluoro-4-phenoxy-2,5-cyclohexadien-1-one, and perfluoro-2-phenoxy-2,5-cyclohexadien-1-one. Antimony and niobium pentafluorides give stable complexes or the corresponding pentafluorophenolates with pentafluorophenol.

• Research Organization: Novosibirsk Institute of Organic Chemistry, Siberian Branch
• OSTI ID: 5910122
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 21:4, PART 2; ISSN JOCYA
• Country of Publication: United States
• Language: English

Related Subjects

02 PETROLEUM
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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ANTIMONY COMPOUNDS
ANTIMONY FLUORIDES
AROMATICS
CHEMICAL PROPERTIES
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
DERIVATIZATION
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HYDROXY COMPOUNDS
KINETICS
NIOBIUM COMPOUNDS
NIOBIUM FLUORIDES
ORGANIC COMPOUNDS
PHENOLATES
PHENOLS
RARE GAS COMPOUNDS
REACTION KINETICS
REFRACTORY METAL COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
VANADIUM COMPOUNDS
VANADIUM FLUORIDES
XENON COMPOUNDS
XENON FLUORIDES
YIELDS