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Alkylation of malonic ester and monoalkylmalonic esters under the conditions of phase-transfer catalysis

Journal Article · · J. Org. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:6035613
; ; ;

Simple procedures were developed for the monoalkylation of malonic ester in the potassium hydroxide-DMFA (DMFA-acetone)-triethylbenzylammonium chloride system and the alkylation of alkylmalonic esters to dialkylmalonic esters in the calcium oxide-DMFA system.

Research Organization:
N.D. Zelinskii Institute of Organic Chemistry, Novokuznetsk, USSR
OSTI ID:
6035613
Journal Information:
J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 21:12; ISSN JOCYA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKALI METAL COMPOUNDS
ALKALINE EARTH METAL COMPOUNDS
ALKYLATING AGENTS
ALKYLATION
AMINES
AMMONIUM CHLORIDES
AMMONIUM COMPOUNDS
AMMONIUM HALIDES
BROMINATED ALIPHATIC HYDROCARBONS
CALCIUM COMPOUNDS
CALCIUM OXIDES
CARBON COMPOUNDS
CARBONATES
CARBOXYLIC ACID ESTERS
CARBOXYLIC ACIDS
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
CHROMATOGRAPHY
DICARBOXYLIC ACIDS
ESTERIFICATION
ESTERS
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HETEROGENEOUS CATALYSIS
HYDROGEN COMPOUNDS
HYDROXIDES
IODINATED ALIPHATIC HYDROCARBONS
MALONIC ACID
MASS SPECTRA
MATERIALS TESTING
METHYL IODIDE
NMR SPECTRA
ORGANIC ACIDS
ORGANIC BROMINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
POTASSIUM CARBONATES
POTASSIUM COMPOUNDS
POTASSIUM HYDROXIDES
QUATERNARY COMPOUNDS
SEPARATION PROCESSES
SODIUM CARBONATES
SODIUM COMPOUNDS
SODIUM HYDROXIDES
SPECTRA
TESTING
YIELDS