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Determination of the isomeric composition and structure of bicyclo(3. 3. 1)nonadienes by PMR spectroscopy

Journal Article · · J. Org. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:6033790

The isomeric composition of bicyclo(3.3.1)nonadienes was investigated by GLC and PMR spectroscopy with silver-lanthanide shift reagents. The absence of stereospecificity in the hydrogenation of 3,7-dimethylenebicyclo(3.3.1)nonane by hydrogen adsorbed on Raney nickel was demonstrated. This is explained by the sequence of the isomerization and then hydrogenation processes.

Research Organization:
Kiev Polytechnic Institute, USSR
OSTI ID:
6033790
Journal Information:
J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 21:8; ISSN JOCYA
Country of Publication:
United States
Language:
English

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