Synthesis of asymmetric derivatives of 3,7-dimethylenebicyclo-(3. 3. 1)nonane

Journal Article · Fri Jan 10 04:00:00 UTC 1986 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6250501

Krasutskii, P A; Chesskaya, N S; Rodionov, V N; Baula, O P; Yurchenko, A G

The fragmentation of asymmetric dibromo derivatives of adamantane was studied in order to synthesize asymmetric 3,7-dimethylenebicyclo(3.3.1)nonanes. A zinc copper couple was used as reagent for the fragmentation. During the fragmentation of methyl bromo(3-bromo-1-adamantyl)acetate isomerization of the exocyclic ..pi.. bond to an endocyclic bond was observed in addition to the fragmentation and reduction products.

• Research Organization: Kiev Polytechnic Institute, USSR
• OSTI ID: 6250501
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 21:8; ISSN JOCYA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACETATES
ADAMANTANE
ALKALI METAL COMPOUNDS
ALKANES
ALUMINIUM COMPOUNDS
ALUMINIUM HYDRIDES
ASYMMETRY
BROMIDES
BROMINATED ALIPHATIC HYDROCARBONS
BROMINE COMPOUNDS
CADMIUM BROMIDES
CADMIUM COMPOUNDS
CADMIUM HALIDES
CARBOXYLIC ACID SALTS
CATALYTIC EFFECTS
CHEMICAL BONDS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHROMATOGRAPHY
COPPER COMPOUNDS
CYCLOALKANES
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDRIDES
HYDROCARBONS
HYDROGEN COMPOUNDS
INFRARED SPECTRA
ISOMERIZATION
KINETICS
LINE WIDTHS
LITHIUM COMPOUNDS
LITHIUM HYDRIDES
NMR SPECTRA
ORGANIC BROMINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
REACTION KINETICS
SEPARATION PROCESSES
SPECTRA
STEREOCHEMISTRY
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
YIELDS
ZINC COMPOUNDS