Synthesis of asymmetric derivatives of 3,7-dimethylenebicyclo-(3. 3. 1)nonane

Journal Article · Fri Jan 10 00:00:00 EST 1986 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6250501

Krasutskii, P A; Chesskaya, N S; Rodionov, V N; Baula, O P; Yurchenko, A G

The fragmentation of asymmetric dibromo derivatives of adamantane was studied in order to synthesize asymmetric 3,7-dimethylenebicyclo(3.3.1)nonanes. A zinc copper couple was used as reagent for the fragmentation. During the fragmentation of methyl bromo(3-bromo-1-adamantyl)acetate isomerization of the exocyclic ..pi.. bond to an endocyclic bond was observed in addition to the fragmentation and reduction products.

• Research Organization: Kiev Polytechnic Institute, USSR
• OSTI ID: 6250501
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Vol. 21:8; Other Information: Translated from Zh. Org. Khim.; 21: No.8, 1677-1684(Aug 1985)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CADMIUM BROMIDES
CATALYTIC EFFECTS
COPPER COMPOUNDS
CYCLOALKANES
SYNTHESIS
ZINC COMPOUNDS
ACETATES
ADAMANTANE
ALUMINIUM HYDRIDES
ASYMMETRY
BROMINATED ALIPHATIC HYDROCARBONS
CHEMICAL BONDS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHROMATOGRAPHY
INFRARED SPECTRA
ISOMERIZATION
LINE WIDTHS
LITHIUM HYDRIDES
NMR SPECTRA
STEREOCHEMISTRY
ALKALI METAL COMPOUNDS
ALKANES
ALUMINIUM COMPOUNDS
BROMIDES
BROMINE COMPOUNDS
CADMIUM COMPOUNDS
CADMIUM HALIDES
CARBOXYLIC ACID SALTS
CHEMICAL REACTIONS
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDRIDES
HYDROCARBONS
HYDROGEN COMPOUNDS
KINETICS
LITHIUM COMPOUNDS
ORGANIC BROMINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
REACTION KINETICS
SEPARATION PROCESSES
SPECTRA
TRANSITION ELEMENT COMPOUNDS
YIELDS
400201* - Chemical & Physicochemical Properties