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Kinetic mechanisms in a 16. mu. m CO/sub 2/ laser

Journal Article · · J. Chem. Phys.; (United States)
OSTI ID:5991706

A rate equation model is used to examine the time evolution of vibrational excitation and subsequent lasing of an optically pumped DF/CO/sub 2/ or HBr/CO/sub 2/ laser. With this model, one may simulate optical pumping of DF/CO/sub 2//He/N/sub 2/ mixtures with a pulsed DF laser, or direct pumping of CO/sub 2/ or HBr/CO/sub 2/ mixtures with an HBr laser. This model includes the simulation of optical saturation at 9.4 ..mu..m. Rotational nonequilibrium phenomena are also included in the models. Model calculations reveal the relative importance of various kinetic relaxation mechanisms. Rotational hole burning effects are observed for all calculations simulating line selected operation. The effect of the strength and duration of the pump laser and the 9.4 ..mu..m saturation pulse are examined. Finally, the model is found to compare well with laboratory observations of pulsed HBr/CO/sub 2/ laser performance.

Research Organization:
Michigan State University, East Lansing, Michigan 48824
OSTI ID:
5991706
Journal Information:
J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 71:5; ISSN JCPSA
Country of Publication:
United States
Language:
English

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