Line parameters for ozone hot bands in the 3. 3-[mu]m spectral region

Journal Article · Sun Aug 01 04:00:00 EDT 1993 · Journal of Molecular Spectroscopy; (United States)

DOI:https://doi.org/10.1006/jmsp.1993.1185· OSTI ID:5984111

Flaud, J M; Camy-Peyret, C; Perrin, A ^[1]; Devi, V M ^[2]; Barbe, A; Bouazza, S; Plateaux, J J ^[3]; Rinsland, C P; Smith, M A.H. ^[4]; Goldman, A ^[5]

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1. Univ. Pierre et Marie Curie, Paris (France). Lab. de Physique Moleculaire et Applications
2. College of William and Mary, Williamsburg, VA (United States). Physics Dept.
3. Univ. de Reims (France). Groupe de Spectroscopie Moleculaire et Atmospherique
4. NASA Langley Research Center, Hampton, VA (United States). Atmospheric Sciences Div.
5. Univ. of Denver, CO (United States). Dept. of Physics

Line positions, intensities, and lower state energies have been calculated for eight hot bands of [sup 16]O[sub 3] in the 3.3-[mu]m spectral region. The results are based on spectroscopic parameters deduced in recent high-resolution laboratory studies and improved rotational energy levels of the (103), (004), and (310) vibrational states derived by refitting earlier data and experimental (004) energy levels from measurements of the 4[nu][sub 3] [minus] [nu][sub 3] hot band. The good quality of the new parameters has been verified through comparisons of line-by-line simulations with high-resolution laboratory spectra. The present work and the results of the analyses of the main bands at 3.6 [mu]m and 3.3 [mu]m provide a complete set of ozone spectroscopic line parameters covering the 3-[mu]m region.

• OSTI ID: 5984111
• Journal Information: Journal of Molecular Spectroscopy; (United States), Journal Name: Journal of Molecular Spectroscopy; (United States) Vol. 160:2; ISSN JMOSA3; ISSN 0022-2852
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400102* -- Chemical & Spectral Procedures
ENERGY LEVELS
EXCITED STATES
INFRARED SPECTRA
OZONE
ROTATIONAL STATES
SPECTRA
VIBRATIONAL STATES