New catalysts for coal-liquid upgrading. Quarterly report, March 1, 1983-May 31, 1983. [More generally various metallophthalocyanines]

Technical Report · Sat Jan 01 04:00:00 EST 1983

OSTI ID:5972861

Boucher, L J

The conversion of quinaldine was compared to that of quinoline using the commercial catalysts: NiMo oxide/Al/sub 2/O/sub 3/ (HT-500E, %NiO = 3.5, %MoO/sub 3/ = 15.5, surface area 200 m/sup 2//g), NiW/Al/sub 2/O/sub 3/ (Harshaw Ni 4301E; %Ni = 6, %W = 19 surface area = 230 m/sup 2//g) CoMo oxide/Al/sub 2/O/sub 3/ (Harshaw CoMo-0603; %CoO = 3, %MoO/sub 3/ = 12, surface area = 166 m/sup 2//g. The rates of hydrogenation of several nitrogen containing heterocycles have been measured at 1000 psi H/sub 2/ pressure and 250 to 350/sup 0/C using (Co(PC)) supported on silica, alumina, silica-alumina. Although our initial reports were to the contrary, present results are consistent with a first order hydrogenation of substrate. For the hydrogenation of quinoline the support influences the rate to a small extent. The various substrates undergo hydrogenation at different rats.

• Research Organization: Western Kentucky Univ., Bowling Green (USA). Dept. of Chemistry
• DOE Contract Number: FG22-81PC40812
• OSTI ID: 5972861
• Report Number(s): DOE/PC/40812-T7; ON: DE83013872
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
010405* -- Coal
Lignite
& Peat-- Hydrogenation & Liquefaction
AZINES
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COAL LIQUEFACTION
COAL LIQUIDS
COBALT COMPOUNDS
COMPARATIVE EVALUATIONS
DATA
EXPERIMENTAL DATA
FLUIDS
HETEROCYCLIC COMPOUNDS
HYDROGENATION
INFORMATION
KINETICS
LIQUEFACTION
LIQUIDS
MOLYBDENUM COMPOUNDS
NICKEL COMPOUNDS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PERFORMANCE TESTING
PROCESSING
PYRIDINES
QUINALDINE
QUINOLINES
REACTION KINETICS
REFINING
STRUCTURAL MODELS
TESTING
THERMOCHEMICAL PROCESSES
TRANSITION ELEMENT COMPOUNDS
TUNGSTEN COMPOUNDS