Optically active 2-arylidene-4-bromo-p-menthan-3-ones and their dehydrobromination products
Journal Article
·
· J. Org. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:5971880
The bromination of (/emdash/)-2-arylidene-p-menthan-3-ones with N-bromosuccinimide in carbon tetrachloride in the presence of an initiator of free radical formation (dicylohexyl peroxydicarbonate) gave the corresponding (/emdash/)-2-arylidene-4-bromo-p-menthan-3-ones. The latter are dehydrobrominated by boiling in pyridine and form (/emdash/)-2-arylidene-4-p-menthan-3-ones.
- Research Organization:
- All-Union Scientific-Research Institute of Single Crystals, Scintillation Materials, and Specially Pure Chemicals, Kharkov (USSR)
- OSTI ID:
- 5971880
- Journal Information:
- J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 24:8; ISSN JOCYA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
BROMINATION
CARBON TETRACHLORIDE
CARBONIC ACID ESTERS
CATALYTIC EFFECTS
CHEMICAL REACTIONS
CHLORINATED ALIPHATIC HYDROCARBONS
CHLOROFORM
COUPLING
COUPLING CONSTANTS
DEHALOGENATION
DEHYDROGENATION
DEUTERIUM COMPOUNDS
DISSOCIATION
ESTERS
HALOGENATED ALIPHATIC HYDROCARBONS
HALOGENATION
HYDROGEN COMPOUNDS
INFRARED SPECTRA
INTERMEDIATE COUPLING
J-J COUPLING
KETONES
MULTIPLETS
NMR SPECTRA
OPTICAL PROPERTIES
ORGANIC BROMINE COMPOUNDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PHYSICAL PROPERTIES
RADICALS
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
400201* -- Chemical & Physicochemical Properties
BROMINATION
CARBON TETRACHLORIDE
CARBONIC ACID ESTERS
CATALYTIC EFFECTS
CHEMICAL REACTIONS
CHLORINATED ALIPHATIC HYDROCARBONS
CHLOROFORM
COUPLING
COUPLING CONSTANTS
DEHALOGENATION
DEHYDROGENATION
DEUTERIUM COMPOUNDS
DISSOCIATION
ESTERS
HALOGENATED ALIPHATIC HYDROCARBONS
HALOGENATION
HYDROGEN COMPOUNDS
INFRARED SPECTRA
INTERMEDIATE COUPLING
J-J COUPLING
KETONES
MULTIPLETS
NMR SPECTRA
OPTICAL PROPERTIES
ORGANIC BROMINE COMPOUNDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PHYSICAL PROPERTIES
RADICALS
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS