Reactions of cyclohexadienes and cyclohexene in the presence of a polyethylenimine complex of palladium dichloride
Journal Article
·
· Dokl. Chem. (Engl. Transl.); (United States)
OSTI ID:5968692
The authors report the results of a study of the catalytic properties of a macromolecular complex between PEI and palladium dichloride in the hydrogenation and disproportionation reactions of cyclohexene, 1,3-cyclohexadiene, and 1,4cyclohexadiene. The kinetic curves of the disproportionation of 1,3-CHD in the presence of 1-hexyne are given. Cyclohexane and benzene were not detected in the reaction mixture. These results demonstrate that disproportionation does not occur under hydrogenation conditions.
- Research Organization:
- A.V. Topchiev Institute of Petrochemical Synthesis
- OSTI ID:
- 5968692
- Journal Information:
- Dokl. Chem. (Engl. Transl.); (United States), Journal Name: Dokl. Chem. (Engl. Transl.); (United States) Vol. 282:1-6; ISSN DKCHA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
02 PETROLEUM
020400* -- Petroleum-- Processing
ALKANES
ALKENES
AROMATICS
BENZENE
CATALYTIC EFFECTS
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
CYCLOALKANES
CYCLOALKENES
CYCLOHEXANE
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
HYDROGENATION
ORGANIC COMPOUNDS
ORGANIC POLYMERS
OXIDATION
PALLADIUM CHLORIDES
PALLADIUM COMPLEXES
PALLADIUM COMPOUNDS
POLYETHYLENES
POLYMERS
POLYOLEFINS
REDUCTION
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
020400* -- Petroleum-- Processing
ALKANES
ALKENES
AROMATICS
BENZENE
CATALYTIC EFFECTS
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
CYCLOALKANES
CYCLOALKENES
CYCLOHEXANE
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
HYDROGENATION
ORGANIC COMPOUNDS
ORGANIC POLYMERS
OXIDATION
PALLADIUM CHLORIDES
PALLADIUM COMPLEXES
PALLADIUM COMPOUNDS
POLYETHYLENES
POLYMERS
POLYOLEFINS
REDUCTION
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS