Kinetics of interaction of hydroperoxides with some disulphides
Journal Article
·
· Pet. Chem. USSR (Engl. Transl.); (United States)
Disulphides catalytically break down tert-butyl and cumyl hydroperoxides. In chlorobenzene breakdown takes place by a bimolecular mechanism at a rate which is directly proportional to the concentration of hydroperoxide and disulphide; the rate constant of this reaction varies from 0.4 to 1.2 1./mole.sec at 373/sup 0/K for disulphides and tert-butyl hydroperoxide, respectively. No radicals are formed by the reaction of tert-butyl hydroperoxide with disulphide. 3 references, 2 figures, 2 tables.
- OSTI ID:
- 5961652
- Journal Information:
- Pet. Chem. USSR (Engl. Transl.); (United States), Journal Name: Pet. Chem. USSR (Engl. Transl.); (United States) Vol. 22:3; ISSN PECHA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALKANES
ANTIOXIDANTS
AROMATICS
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORINATED AROMATIC HYDROCARBONS
COMPARATIVE EVALUATIONS
CUMENE
DATA
DATA ANALYSIS
DECOMPOSITION
EXPERIMENTAL DATA
HALOGENATED AROMATIC HYDROCARBONS
HYDROCARBONS
INFORMATION
INHIBITION
IODOMETRY
KINETICS
NUMERICAL DATA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
OXYGEN COMPOUNDS
PEROXIDES
QUANTITY RATIO
REACTION KINETICS
SULFIDES
SULFUR COMPOUNDS
TIME DEPENDENCE
TITRATION
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALKANES
ANTIOXIDANTS
AROMATICS
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORINATED AROMATIC HYDROCARBONS
COMPARATIVE EVALUATIONS
CUMENE
DATA
DATA ANALYSIS
DECOMPOSITION
EXPERIMENTAL DATA
HALOGENATED AROMATIC HYDROCARBONS
HYDROCARBONS
INFORMATION
INHIBITION
IODOMETRY
KINETICS
NUMERICAL DATA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
OXYGEN COMPOUNDS
PEROXIDES
QUANTITY RATIO
REACTION KINETICS
SULFIDES
SULFUR COMPOUNDS
TIME DEPENDENCE
TITRATION