Near perfect complementarity of equilibrium isotope effects: a corrected value for a recently published equilibrium constant derived for the 2-norbornyl-h/sub 10/d/sub 1/ cation
Journal Article
·
· J. Org. Chem.; (United States)
A study was made to redetermine the primary isotope rate constant ratios (k/sub h/ / k/sub d/) for the 2-norbornyl-h/sub 10/d/sub 1/ cation. Recent results suggested that this reanalysis was in order. It was found that the 6,2(1)-hydride-(deuteride) shift in the 2-norbornyl cation is highly stereospecific and that the 2-norbornyl cation is either symmetrical or a pair of nearly symmetrical cations separated by a very low potential barrier.
- Research Organization:
- Univ. of Calgary, Alberta
- OSTI ID:
- 5959986
- Journal Information:
- J. Org. Chem.; (United States), Journal Name: J. Org. Chem.; (United States) Vol. 49:22; ISSN JOCEA
- Country of Publication:
- United States
- Language:
- English
Similar Records
Hydride shifts in the 2-norbornyl cation
Organic chemistry, catalysis, and coal research
Isotopic perturbation effects on a single averaged NMR peak: norbornyl cation
Thesis/Dissertation
·
Fri Aug 01 00:00:00 EDT 1975
·
OSTI ID:4096966
Organic chemistry, catalysis, and coal research
Technical Report
·
Sat Jan 31 23:00:00 EST 1976
·
OSTI ID:4089546
Isotopic perturbation effects on a single averaged NMR peak: norbornyl cation
Journal Article
·
Sat Jun 11 00:00:00 EDT 1983
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:5555141
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400302* -- Organic Chemistry-- Isotope Effects-- (-1987)
ALKANES
CATIONS
CHARGED PARTICLES
CHEMICAL ANALYSIS
CHEMICAL REACTION KINETICS
CYCLOALKANES
DATA
DEUTERIUM
ELEMENTS
EXPERIMENTAL DATA
FREQUENCY RANGE
HYDROCARBONS
HYDROGEN
HYDROGEN ISOTOPES
INFORMATION
IONS
ISOTOPE EFFECTS
ISOTOPES
KINETICS
LIGHT NUCLEI
LOW TEMPERATURE
MHZ RANGE
MHZ RANGE 01-100
MHZ RANGE 100-1000
MOLECULAR STRUCTURE
NMR SPECTRA
NONMETALS
NUCLEI
NUMERICAL DATA
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
QUANTITATIVE CHEMICAL ANALYSIS
REACTION KINETICS
SPECTRA
STABLE ISOTOPES
STEREOCHEMISTRY
400302* -- Organic Chemistry-- Isotope Effects-- (-1987)
ALKANES
CATIONS
CHARGED PARTICLES
CHEMICAL ANALYSIS
CHEMICAL REACTION KINETICS
CYCLOALKANES
DATA
DEUTERIUM
ELEMENTS
EXPERIMENTAL DATA
FREQUENCY RANGE
HYDROCARBONS
HYDROGEN
HYDROGEN ISOTOPES
INFORMATION
IONS
ISOTOPE EFFECTS
ISOTOPES
KINETICS
LIGHT NUCLEI
LOW TEMPERATURE
MHZ RANGE
MHZ RANGE 01-100
MHZ RANGE 100-1000
MOLECULAR STRUCTURE
NMR SPECTRA
NONMETALS
NUCLEI
NUMERICAL DATA
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
QUANTITATIVE CHEMICAL ANALYSIS
REACTION KINETICS
SPECTRA
STABLE ISOTOPES
STEREOCHEMISTRY