Organic chemistry, catalysis, and coal research
Technical Report
·
OSTI ID:4089546
The structure of homoadamantane was investigated by NMR studies of the deuterium-labeled 4-homoadamantyl cation. In order to evaluate the ratio of endo, endo-6,2-hydride(6,2-H)-exo, exo-3,2-hydride(3,2-H) shifts in the 2- norbornyl cation, two related compounds were synthesized and solvolyzed. They are: 2-methyl-2-($delta$$sup 3$-cyclopentenyl-1-d)-propyl nosylate and (+)-2-endo- camphenilyl-2-exo-d brosylate. A systematic study of charge-transfer complexes in an effort to synthesize organic conductors is reported. In studies on the catalytic hydrodesulfurization of coal, the role of low concentrations of H$sub 2$S in hydrogen on a commercial Co--Mo catalyst was investigated. Progress in research on the use of molten-salt catalysts in the hydrogasification of coal is reported. Results of experiments are reported in which thin films of carbon evaporated onto silica plates were partly overlaid with evaporated Ni in order to make microscopic observations of the catalysis of the reaction of carbon with hydrogen gas. Computer programs have been written for simulating a methanation reactor and a methane--steam reformer. (JGB)
- Research Organization:
- Oak Ridge National Lab., Tenn. (USA)
- NSA Number:
- NSA-33-028437
- OSTI ID:
- 4089546
- Report Number(s):
- ORNL--5111
- Country of Publication:
- United States
- Language:
- English
Similar Records
Hydride shifts in the 2-norbornyl cation
Structural effects in solvolytic reactions. XXVI. A critical study of the effect of solvent on the exo:endo rate ratio in the solvolysis of 2-norbornyl derivatives. Evidence that the exo:endo rate ratio is not the result of K/sub. delta. //K/sub s/ processes
Near perfect complementarity of equilibrium isotope effects: a corrected value for a recently published equilibrium constant derived for the 2-norbornyl-h/sub 10/d/sub 1/ cation
Thesis/Dissertation
·
Fri Aug 01 00:00:00 EDT 1975
·
OSTI ID:4096966
Structural effects in solvolytic reactions. XXVI. A critical study of the effect of solvent on the exo:endo rate ratio in the solvolysis of 2-norbornyl derivatives. Evidence that the exo:endo rate ratio is not the result of K/sub. delta. //K/sub s/ processes
Journal Article
·
Wed May 10 00:00:00 EDT 1978
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:6651484
Near perfect complementarity of equilibrium isotope effects: a corrected value for a recently published equilibrium constant derived for the 2-norbornyl-h/sub 10/d/sub 1/ cation
Journal Article
·
Thu Nov 01 23:00:00 EST 1984
· J. Org. Chem.; (United States)
·
OSTI ID:5959986
Related Subjects
400301* --Chemistry--Organic Chemistry--Chemical & Physicochemical Properties
ADAMANTANE-- DEUTERIUM COMPOUNDS-- ELECTRON SPIN RESONANCE-- LABELLING-- MOLECULAR STRUCTURE
CARBON MONOXIDE-- CHEMICAL REACTIONS-- COMPUTER CODES-- HYDROGEN-- METHANATION-- METHANE-- STEAM
CARBON-- CATALYSIS-- ELECTRON MICROSCOPY-- FILMS-- NICKEL
CATALYSTS-- CHEMICAL REACTIONS-- COBALT-- HYDROGEN SULFIDES-- MOLYBDENUM
CATALYSTS-- COAL-- COAL GASIFICATION-- HYDROGENATION-- MOLTEN SALTS
CHEMICAL PREPARATION-- ELECTRIC CONDUCTORS-- ORGANIC COMPOUNDS
N40210* --Chemistry--Inorganic
Organic
& Physical Chemistry--Chemical & Physiochemical Properties
RESEARCH PROGRAMS AROMATICS-- CHEMICAL PREPARATION-- ORGANIC BROMINE COMPOUNDS-- SOLVOLYSIS-- SULFONIC ACID ESTERS
ADAMANTANE-- DEUTERIUM COMPOUNDS-- ELECTRON SPIN RESONANCE-- LABELLING-- MOLECULAR STRUCTURE
CARBON MONOXIDE-- CHEMICAL REACTIONS-- COMPUTER CODES-- HYDROGEN-- METHANATION-- METHANE-- STEAM
CARBON-- CATALYSIS-- ELECTRON MICROSCOPY-- FILMS-- NICKEL
CATALYSTS-- CHEMICAL REACTIONS-- COBALT-- HYDROGEN SULFIDES-- MOLYBDENUM
CATALYSTS-- COAL-- COAL GASIFICATION-- HYDROGENATION-- MOLTEN SALTS
CHEMICAL PREPARATION-- ELECTRIC CONDUCTORS-- ORGANIC COMPOUNDS
N40210* --Chemistry--Inorganic
Organic
& Physical Chemistry--Chemical & Physiochemical Properties
RESEARCH PROGRAMS AROMATICS-- CHEMICAL PREPARATION-- ORGANIC BROMINE COMPOUNDS-- SOLVOLYSIS-- SULFONIC ACID ESTERS