Kinetics of reactions of solvated electrons with radiolysis products of aliphatic monohydric alcohols

Journal Article · Thu Sep 01 00:00:00 EDT 1988 · High Energy Chem. (Engl. Transl.); (United States)

OSTI ID:5948812

Ponomarev, A V; Pikaev, A K

To clarify the mechanism of radiolytic transformations in alcoholic systems, information is required on the kinetics of reactions of solvated electrons with alcohols and their principal radiolysis products: alkoxonium ions and carbonyl compounds. We comparatively measured the kinetics of reactions in methanol, ethanol, 1-propanol, 2-propanol, and 1-butanol by a pulsed radiolysis method. We used a rapid action spectrophotometric apparatus for a nanosecond pulsed radiolysis a microsecond pulsed radiolysis apparatus.

• OSTI ID: 5948812
• Journal Information: High Energy Chem. (Engl. Transl.); (United States), Journal Name: High Energy Chem. (Engl. Transl.); (United States) Vol. 22:2; ISSN HIECA
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
ACETONE
ALCOHOLS
ALDEHYDES
BEAMS
BUTANOLS
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMISTRY
DECOMPOSITION
ELECTRON BEAMS
ELECTRONS
ELEMENTARY PARTICLES
EQUATIONS
ETHANOL
FERMIONS
HYDROXY COMPOUNDS
KETONES
KINETIC EQUATIONS
KINETICS
LEPTON BEAMS
LEPTONS
METHANOL
ORGANIC COMPOUNDS
PARTICLE BEAMS
PROPANOLS
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIOLYSIS
REACTION KINETICS
SOLVATED ELECTRONS
SPECTROPHOTOMETRY