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Mechanism of radiolytic reduction of nitro-substituted tetrazoliumsalts in isopropanol

Journal Article · · High Energy Chem. (Engl. Transl.); (United States)
OSTI ID:5948803
; ; ;
The mechanism of the radiolytic transformations of nitro-substituted tetrazolium salts in isopropanol was studied by the methods of pulsed and stationary radiolysis. It was found that solvated electrons and (CH/sub 3/)/sub 2/COH radicals reduce the tetrazolium salt to tetrazolium radicals. Rate constants of the corresponding reacittns were measured, and the absorption spectra of these radicals were recorded.
OSTI ID:
5948803
Journal Information:
High Energy Chem. (Engl. Transl.); (United States), Journal Name: High Energy Chem. (Engl. Transl.); (United States) Vol. 21:6; ISSN HIECA
Country of Publication:
United States
Language:
English

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Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
ABSORPTION SPECTRA
ALCOHOLS
AZOLES
BETA DECAY RADIOISOTOPES
BETA-MINUS DECAY RADIOISOTOPES
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMISTRY
COBALT 60
COBALT ISOTOPES
DECOMPOSITION
ELECTROMAGNETIC RADIATION
ELECTRONS
ELEMENTARY PARTICLES
FERMIONS
GAMMA RADIATION
HETEROCYCLIC COMPOUNDS
HYDROXY COMPOUNDS
INTERMEDIATE MASS NUCLEI
INTERNAL CONVERSION RADIOISOTOPES
IONIZING RADIATIONS
IRRADIATION
ISOMERIC TRANSITION ISOTOPES
ISOTOPES
KINETICS
LEPTONS
MINUTES LIVING RADIOISOTOPES
NITRO COMPOUNDS
NUCLEI
ODD-ODD NUCLEI
ORGANIC BROMINE COMPOUNDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PROPANOLS
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIATIONS
RADICALS
RADIOISOTOPES
RADIOLYSIS
REACTION KINETICS
REDUCTION
SOLVATED ELECTRONS
SPECTRA
TETRAZOLES
YEARS LIVING RADIOISOT