Photosynthesis of methylamine and ethylenediamine involving amino acids from gas mixtures of methane, ammonia, and water
Conference
·
· Am. Chem. Soc., Div. Pet. Chem., Prepr.; (United States)
OSTI ID:5899307
The photochemical reaction of the mixtures of CH/sub 4/, NH/sub 3/, and H/sub 2/O has been applied to achieve the chemical activation of methane. The photolysis of the mixtures with a low-pressure mercury lamp led to the formation of considerable amounts of methylamine and ethyl-enediamine with a small quantity of amino acids in addition to oxygen-containing species, ethane, and hydrogen. CH/sub 2/NH/sub 2/ radicals formed during the photolysis were detected by ESR applying spin trap technique, and it was suggested that the coupling of these radicals leads to the formation of ethylenediamine.
- Research Organization:
- Yamaguchi Univ., Tokiwadai (Japan)
- OSTI ID:
- 5899307
- Report Number(s):
- CONF-8809266-
- Journal Information:
- Am. Chem. Soc., Div. Pet. Chem., Prepr.; (United States), Journal Name: Am. Chem. Soc., Div. Pet. Chem., Prepr.; (United States) Vol. 33:3; ISSN ACPCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
03 NATURAL GAS
033000 -- Natural Gas-- Properties & Composition
090310 -- Inorganic Hydrogen Compound Fuels-- Properties-- (1976-1989)
10 SYNTHETIC FUELS
14 SOLAR ENERGY
140505* -- Solar Energy Conversion-- Photochemical
Photobiological
& Thermochemical Conversion-- (1980-)
ALKANES
ALKENES
AMINES
AMINO ACIDS
AMMONIA
CARBOXYLIC ACIDS
CHEMICAL PREPARATION
CHEMICAL REACTIONS
CHEMISTRY
DATA
DECOMPOSITION
ELECTRON SPIN RESONANCE
EXPERIMENTAL DATA
FLUIDS
GASES
HYDRIDES
HYDROCARBONS
HYDROGEN COMPOUNDS
INFORMATION
MAGNETIC RESONANCE
METHANE
METHYLAMINE
NITROGEN COMPOUNDS
NITROGEN HYDRIDES
NUMERICAL DATA
ORGANIC ACIDS
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOCHEMISTRY
PHOTOLYSIS
PHOTOSYNTHESIS
RADICALS
RESONANCE
SYNTHESIS
WATER
033000 -- Natural Gas-- Properties & Composition
090310 -- Inorganic Hydrogen Compound Fuels-- Properties-- (1976-1989)
10 SYNTHETIC FUELS
14 SOLAR ENERGY
140505* -- Solar Energy Conversion-- Photochemical
Photobiological
& Thermochemical Conversion-- (1980-)
ALKANES
ALKENES
AMINES
AMINO ACIDS
AMMONIA
CARBOXYLIC ACIDS
CHEMICAL PREPARATION
CHEMICAL REACTIONS
CHEMISTRY
DATA
DECOMPOSITION
ELECTRON SPIN RESONANCE
EXPERIMENTAL DATA
FLUIDS
GASES
HYDRIDES
HYDROCARBONS
HYDROGEN COMPOUNDS
INFORMATION
MAGNETIC RESONANCE
METHANE
METHYLAMINE
NITROGEN COMPOUNDS
NITROGEN HYDRIDES
NUMERICAL DATA
ORGANIC ACIDS
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOCHEMISTRY
PHOTOLYSIS
PHOTOSYNTHESIS
RADICALS
RESONANCE
SYNTHESIS
WATER