THE PHOTOCHEMISTRY OF METHYLAMINE
Journal Article
·
· Journal of the American Chemical Society (U.S.)
Hydrogen, methane, nitrogen, ethane, ammonia, ethylenimine, dimethylamine, azomethane, and a polymer were identified as products in the photochemical decomposition of methylamine. Quantum yields of most of these products were determined under a variety of experimental conditions at room temperature. By use of CH/sub 3/ND/sub 2/ and of CD/sub 3/NH/sub 2/ as well as by use of scavengers, it was shown that the main primary process is the elimination of a hydrogen atom. This is followed by abstraction from the substrate to form hydrogen gas. Other steps in the mechanism are suggested and evidence for some of them presented. (auth)
- Research Organization:
- Univ. of Rochester, N.Y.
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-17-025099
- OSTI ID:
- 4703397
- Journal Information:
- Journal of the American Chemical Society (U.S.), Journal Name: Journal of the American Chemical Society (U.S.) Vol. Vol: 85; ISSN JACSA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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