Synthesis, structure, and characteristics of compounds with a chalcogen-nitrogen bond. IX. Reaction of N-sulfonylselenimides with aromatic aldehydes

Journal Article · Sat Nov 19 23:00:00 EST 1988 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5887766

Naddaka, V I; Avanesyan, K V; Cherkinskaya, M L; Minkin, V I

Earlier the authors showed that N-sulfonyltellurimides react with aromatic aldehydes to form N-sulfonylazomethines. In order to investigate the relationships governing the effect of the nature of the chalcogen on the reactivity on chalcogen imides in the present work they studied the analogous reaction of N-sulfonylselenimides. They established that N-sulfonylselenimides enter into reaction with aromatic aldehydes leading to the formation of N-sulfonylazomethines. This reaction forms the basis of the catalytic action of selenimides during the condensation of aldehydes with sulfonamides.

• Research Organization: M.A. Suslov Rostov State Univ (USSR)
• OSTI ID: 5887766
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 24:6; ISSN JOCYA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALDEHYDES
AMIDES
ANTI-INFECTIVE AGENTS
ANTIMICROBIAL AGENTS
AROMATICS
AZO COMPOUNDS
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
DEHYDROCYCLIZATION
DRUGS
ENERGY
IMIDES
INFRARED SPECTRA
KINETICS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
ORGANOMETALLIC COMPOUNDS
REACTION KINETICS
SELENIUM COMPOUNDS
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
SULFONAMIDES
SYNTHESIS
YIELDS