Kinetic laws and mechanism of the initiation of the polymerization of methyl methacrylate in systems consisting of a chloride of a nontransition element of group III or IV and tert-butyl hydroperoxide
Journal Article
·
· J. Gen. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:5887243
The compositions and yields of the products of the transformation of tert-butyl hydroperoxide under the influence of chlorides in ethyl acetate are shown and the differential kinetics of the decomposition of the hydroperoxide and the accumulation of its main transformation products are presented. The kinetic and activation parameters of the process of decomposition of tert-butyl hydroperoxide are shown. The initiation of the polymerization of methy methacrylate by the system MCl/sub n-t/-BuOOH went with the participation of the complex MCl/sub n-t/-BuOOH; the transformation of the complex in a medium of the monomer takes simultaneous heterolytic and free-radical course.
- Research Organization:
- N.I. Lobachevskii Gor'kii State Univ. (USSR)
- OSTI ID:
- 5887243
- Journal Information:
- J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 57:8; ISSN JGCHA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACETONE
ACTIVATION ENERGY
ALCOHOLS
ALKENES
ALUMINIUM CHLORIDES
ALUMINIUM COMPOUNDS
BUTANOLS
BUTENES
CARBOXYLIC ACID ESTERS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXOMETRY
ENERGY
ESTERS
GERMANIUM CHLORIDES
GERMANIUM COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
HYDROXY COMPOUNDS
KETONES
KINETICS
METHACRYLIC ACID ESTERS
METHANOL
METHYL METHACRYLATE
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
PEROXIDES
POLYMERIZATION
REACTION KINETICS
TIN CHLORIDES
TIN COMPOUNDS
TIN HALIDES
YIELDS
400201* -- Chemical & Physicochemical Properties
ACETONE
ACTIVATION ENERGY
ALCOHOLS
ALKENES
ALUMINIUM CHLORIDES
ALUMINIUM COMPOUNDS
BUTANOLS
BUTENES
CARBOXYLIC ACID ESTERS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXOMETRY
ENERGY
ESTERS
GERMANIUM CHLORIDES
GERMANIUM COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
HYDROXY COMPOUNDS
KETONES
KINETICS
METHACRYLIC ACID ESTERS
METHANOL
METHYL METHACRYLATE
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
PEROXIDES
POLYMERIZATION
REACTION KINETICS
TIN CHLORIDES
TIN COMPOUNDS
TIN HALIDES
YIELDS