Some features of the oxidative conversion of Mo(CO)/sub 6/ in a medium of hydroperoxide or tert-butyl hydroperoxide and an aromatic hydrocarbon
Journal Article
·
· J. Gen. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:6007729
Occurrence of the reaction under study was followed from the decrease in hydroperoxide or of Mo(CO)/sub 6/. The Mo(CO)/sub 6/ content of the reaction was found by determining either the concentration of this compound directly or by determining the concentration of the gaseous products from its transformations (CO + CO/sub 2/). Hydroperoxides (I) and (II) were determined iodometrically. Metal-containing products of the oxidation of Mo(CO)/sub 6/, molybdenum oxides and peroxides, were analyzed by IR and ESR spectroscopy, elemental analysis, and iodometry. Analysis of transformation products of the hydroperoxides (phenol, acetone, dimethylphenylcarbinol, acetophenone, tert-butyl alcohol, water, and oxygen) was performed using gas chromatography. Results are presented.
- Research Organization:
- N.I. Lobachevskii Gor'kii State Univ. (USSR)
- OSTI ID:
- 6007729
- Journal Information:
- J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 57:9; ISSN JGCHA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKYLATED AROMATICS
AROMATICS
BENZENE
CARBONYLS
CHALCOGENIDES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHROMATOGRAPHY
COMPLEXES
DECOMPOSITION
ELECTRON SPIN RESONANCE
GAS CHROMATOGRAPHY
HYDROCARBONS
INFRARED SPECTRA
IODOMETRY
KINETICS
MAGNETIC RESONANCE
MOLYBDENUM COMPLEXES
MOLYBDENUM COMPOUNDS
MOLYBDENUM OXIDES
ORGANIC COMPOUNDS
OXIDATION
OXIDES
OXYGEN COMPOUNDS
PEROXIDES
QUANTITY RATIO
REACTION KINETICS
REFRACTORY METAL COMPOUNDS
RESONANCE
SEPARATION PROCESSES
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
TITRATION
TOLUENE
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
XYLENE-PARA
XYLENES
400201* -- Chemical & Physicochemical Properties
ALKYLATED AROMATICS
AROMATICS
BENZENE
CARBONYLS
CHALCOGENIDES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHROMATOGRAPHY
COMPLEXES
DECOMPOSITION
ELECTRON SPIN RESONANCE
GAS CHROMATOGRAPHY
HYDROCARBONS
INFRARED SPECTRA
IODOMETRY
KINETICS
MAGNETIC RESONANCE
MOLYBDENUM COMPLEXES
MOLYBDENUM COMPOUNDS
MOLYBDENUM OXIDES
ORGANIC COMPOUNDS
OXIDATION
OXIDES
OXYGEN COMPOUNDS
PEROXIDES
QUANTITY RATIO
REACTION KINETICS
REFRACTORY METAL COMPOUNDS
RESONANCE
SEPARATION PROCESSES
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
TITRATION
TOLUENE
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
XYLENE-PARA
XYLENES