Study of the complex formation of vanadium (IV) with organoarsenic compounds by the ESR method

Journal Article · Sun Jan 10 04:00:00 EST 1988 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5887225

Ivanova, A K; Il'yasov, A V; Koshkina, G N; Gel'fond, A S; Akhmadullina, F Yu

The organoarsenic(III) compounds studied were C/sub 6/H/sub 5/AsPr/sub 2/, m-CH/sub 3/C/sub 6/H/sub 4/AsEt/sub 2/, FC/sub 6/H/sub 4/AsEt/sub 2/, p-ClC/sub 6/H/sub 4/AsEt/sub 2/, CH/sub 3/OC/sub 6/H/sub 4/AsEt/sub 2/, p-(CH/sub 3/)/sub 2/NC/sub 6/H/sub 4/AsEt/sub 2/, (ClC/sub 6/H/sub 4/)/sub 2/AsEt, AsEt/sub 3/, (CH/sub 3/C/sub 6/H/sub 4/)/sub 2/, AsEt, and (FC/sub 6/H/sub 4/)/sub 2/AsEt. In the reactions of VCl/sub 4/ and VOCl/sub 2/ with these ligands, complex compounds of two types were formed. The complex (I) contained two molecules of the ligand in the inner sphere, while the complex (II) contained one molecule. The coordination of the As(III) compounds to the central atom in the complex was effected through the arsenic atom.

• Research Organization: S.M. Kirov Kazan' Institute of Chemical Technology (USSR)
• OSTI ID: 5887225
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 57:7; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ALKYLATED AROMATICS
AROMATICS
ARSENIC 75
ARSENIC COMPOUNDS
ARSENIC ISOTOPES
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
COMPLEXOMETRY
COORDINATION VALENCES
ELECTRON SPIN RESONANCE
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
HYPERFINE STRUCTURE
INTERMEDIATE MASS NUCLEI
ISOMERIC TRANSITION ISOTOPES
ISOTOPES
LIGANDS
MAGNETIC RESONANCE
NUCLEI
ODD-EVEN NUCLEI
ORGANIC ARSENIC COMPOUNDS
ORGANIC COMPOUNDS
RADIOISOTOPES
RESONANCE
SECONDS LIVING RADIOISOTOPES
STABLE ISOTOPES
TOLUENE
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
VALENCE
VANADIUM 51
VANADIUM CHLORIDES
VANADIUM COMPLEXES
VANADIUM COMPOUNDS
VANADIUM ISOTOPES