THE HYDROGEN-VANADIUM(V) OXYTRICHLORIDE REACTION
Journal Article
·
· J. Inorg. & Nuclear Chem.
The reaction of hydrogen and VOCl/sub 3/ was investigated over the temperature range from 500 to 850 deg C. Pure VOCl was obtained as the reaction product at 600 to 635 deg C; but at higher temperatures mixtures of V/sub 2/O/sub 3/, VCl/sub 2/, and VOCl resulted. Thermal decomposition of VOCl at 650 to 900 deg C proceeded with the formation of V/sub 2/O/sub 3/, VCl/sub 2/, VCl/sub 3/, and VCl/sub 4/; this reaction was related in a definite way to the hydrogen reduction. X-ray powder diffraction data are given for VOCl and VCl/sub 2/. (auth)
- Research Organization:
- Ames Lab., Ames, Iowa
- NSA Number:
- NSA-15-010792
- OSTI ID:
- 4087403
- Report Number(s):
- IS-58
- Journal Information:
- J. Inorg. & Nuclear Chem., Journal Name: J. Inorg. & Nuclear Chem. Vol. Vol: 15
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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