Oxidation/pyrolysis chemistry as related to fuel scooting tendencies
Conference
·
· Prepr. Pap., Am. Chem. Soc., Div. Fuel Chem.; (United States)
OSTI ID:5886677
The relationships between flame studies of the sooting tendencies of various hydrocarbon fuels and chemical mechanisms derived from flow reactor experiments have been developed. The mechanisms for the oxidation of benzene and butadiene, in particular, have been related to both sooting premixed and diffusion flames despite the large difference in basic flame structure. A recently developed soot formation mechanism has provided the linking framework between chemical mechanism and observable sooting tendencies. The same framework has permitted the application of flow reactor based chemical models to the prediction and explanation of the effect of oxygen addition on sooting diffusion flames.
- Research Organization:
- Princeton Univ., NJ (USA)
- OSTI ID:
- 5886677
- Report Number(s):
- CONF-870802-
- Conference Information:
- Journal Name: Prepr. Pap., Am. Chem. Soc., Div. Fuel Chem.; (United States) Journal Volume: 32:3
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
01 COAL, LIGNITE, AND PEAT
010409 -- Coal
Lignite
& Peat-- Pyrolysis & Carbonization-- (1987-)
010600 -- Coal
Lignite
& Peat-- Properties & Composition
02 PETROLEUM
023000 -- Petroleum-- Properties & Composition
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400800* -- Combustion
Pyrolysis
& High-Temperature Chemistry
AROMATICS
BENZENE
BUTADIENE
CHEMICAL PREPARATION
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
DATA
DECOMPOSITION
DIENES
DIFFUSION
EXPERIMENTAL DATA
FLAMES
FUELS
HYDROCARBONS
INFORMATION
KINETICS
MATHEMATICAL MODELS
NUMERICAL DATA
ORGANIC COMPOUNDS
OXIDATION
POLYENES
PYROLYSIS
REACTION INTERMEDIATES
REACTION KINETICS
SOOT
SYNTHESIS
THERMOCHEMICAL PROCESSES
010409 -- Coal
Lignite
& Peat-- Pyrolysis & Carbonization-- (1987-)
010600 -- Coal
Lignite
& Peat-- Properties & Composition
02 PETROLEUM
023000 -- Petroleum-- Properties & Composition
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400800* -- Combustion
Pyrolysis
& High-Temperature Chemistry
AROMATICS
BENZENE
BUTADIENE
CHEMICAL PREPARATION
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
DATA
DECOMPOSITION
DIENES
DIFFUSION
EXPERIMENTAL DATA
FLAMES
FUELS
HYDROCARBONS
INFORMATION
KINETICS
MATHEMATICAL MODELS
NUMERICAL DATA
ORGANIC COMPOUNDS
OXIDATION
POLYENES
PYROLYSIS
REACTION INTERMEDIATES
REACTION KINETICS
SOOT
SYNTHESIS
THERMOCHEMICAL PROCESSES