Rb-Sr isotope systematics of granitic soil chronosequence: The importance of biotite weathering

Journal Article · Fri Aug 01 04:00:00 EDT 1997 · Geochimica et Cosmochimica Acta

DOI:https://doi.org/10.1016/S0016-7037(97)00148-8· OSTI ID:585149

Blum, J D ^[1]; Erel, Y ^[2]

---

1. Dartmouth College, Hanover, NH (United States)
2. Hebrew Univ., Jerusalem (Israel)

The Rb-Sr isotope systematics of bedrock, soil digests, and the cation exchange fraction of soils from a granitic glacial soil chronosequence in the Wind River Mountains, Wyoming, USA, were investigated. Six soil profiles ranging in age from 0.4 to {approximately}300 kyr were studied and revealed that the {sup 87}Sr/{sup 86}Sr ratio of exchangeable strontium in the B-horizons decreased from 0.7947 to 0.7114 with increasing soil age. Soil digests of the same samples showed much smaller variation in {sup 87}Sr/{sup 86}Sr from 0.7272 to 0.7103 and also generally decreased with increasing soil age. Elevation of the {sup 87}Sr/{sup 86}Sr ratios of Sr released by weathering over the soil digest and bedrock values results from the rapid weathering of biotite to form hydrobiotite and vermiculite in the younger soils. Biotite is estimated to weather at approximately eight times the rate of plagioclase (per gram of mineral) in the youngest soil profile and decreases to a rate of only {approximately}20% of that of plagioclase in the oldest soil. {sup 87}Rb/{sup 86}Sr ratios of the soil cation exchange fraction are estimated to be depleted by factors of up to 11 over the {sup 87}Sr/{sup 86}Sr ratios released by weathering, due to ion exchange partitioning. This study demonstrates that the {sup 87}Sr/{sup 86}Sr ratio released by weathering of crystalline rocks can deviate significantly from bedrock values, and that in soils less than {approximately}20 kyr in age which contain biotite in the soil parent material, weathering-derived {sup 87}Sr/{sup 86}Sr values can be elevated so dramatically that this factor must be considered in estimations of weathering rates based on strontium isotopes. 54 refs., 3 figs., 4 tabs.

• OSTI ID: 585149
• Journal Information: Geochimica et Cosmochimica Acta, Journal Name: Geochimica et Cosmochimica Acta Journal Issue: 15 Vol. 61; ISSN 0016-7037; ISSN GCACAK
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
58 GEOSCIENCES
BIOGEOCHEMISTRY
BIOTITE
ISOTOPE RATIO
STRATIGRAPHY
STRONTIUM
TRACER TECHNIQUES
WEATHERING
WYOMING