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Determination of the composition of cuprous chloride complexes participating in the hydration of methylacetylene in the system CuCl-NH/sub 4/Cl-RSH

Journal Article · · Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:5831153
; ;
Addition of Cu(I) and Cu(II) as well as thiols and certain other sulfur-containing compounds to a cuprous chloride catalyst accelerates the hydration of methylacetylene and acetylene and also produces a marked change in the direction of addition of water to substituted acetylenes. In this paper the dependence of the rate of hydration of methylacetylene on the activity of Cu(I) and chloride ions has been studied under steady-state conditions in a gradientless reactor at 80/degree/C. The composition of the catalytically active complexes taking part in the hydration of methylacetylene is discussed.
Research Organization:
M.V. Lomonosov Moscow State Univ. (USSR)
OSTI ID:
5831153
Journal Information:
Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 29:4; ISSN KICAA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACETONE
ACTIVATION ENERGY
ALDEHYDES
ALKYNES
AMMONIUM CHLORIDES
AMMONIUM COMPOUNDS
AMMONIUM HALIDES
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL COMPOSITION
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
COPPER CHLORIDES
COPPER COMPLEXES
COPPER COMPOUNDS
COPPER HALIDES
DECOMPOSITION
ENERGY
EQUATIONS
HALIDES
HALOGEN COMPOUNDS
HYDRATION
HYDROCARBONS
HYDROCHLORIC ACID
HYDROGEN COMPOUNDS
HYDROLYSIS
INORGANIC ACIDS
KETONES
KINETIC EQUATIONS
KINETICS
LYSIS
MATERIALS TESTING
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PROPYNE
QUANTITY RATIO
REACTION KINETICS
SOLVATION
SOLVOLYSIS
TESTING
THIOLS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
YIELDS