Mo(CO)/sub 6/-promoted reductive cleavage of the carbon-sulfur bond

Journal Article · Thu Dec 12 23:00:00 EST 1985 · J. Org. Chem.; (United States)

DOI:https://doi.org/10.1021/jo00225a091· OSTI ID:5814843

Luh, T Y; Wong, C S

In order to study the reductive cleavage of carbon-sulfur bonds by Mo(CO/sub 6/, various organosulfur compounds are reacted with Mo(CO)/sub 6/ in THF. Results of these experiments demonstrate that benzylic-, aryl-, or ..cap alpha..-acyl-activated carbon-sulfur bonds are reduced by treatment with Mo(CO)/sub 6/. 1 table.

• Research Organization: Chinese Univ. of Hong Kong
• OSTI ID: 5814843
• Journal Information: J. Org. Chem.; (United States), Journal Name: J. Org. Chem.; (United States) Vol. 50:25; ISSN JOCEA
• Country of Publication: United States
• Language: English

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CARBON
CARBONYLS
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL BONDS
CHEMICAL REACTIONS
DATA
DESULFURIZATION
ELEMENTS
ETHERS
EXPERIMENTAL DATA
FURANS
HETEROCYCLIC COMPOUNDS
INFORMATION
MOLYBDENUM COMPOUNDS
NONMETALS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
REDUCTION
REFRACTORY METAL COMPOUNDS
SULFUR
TETRAHYDROFURAN
THIOLS
TRANSITION ELEMENT COMPOUNDS