Synthesis and /sup 1/H and /sup 31/P NMR spectral characteristics of 2-substituted and 2,2-disubstituted 5-phenyl-5-thio-1,3,5-dioxaphosphorinanes
Journal Article
·
· Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
The authors have studied the reactions of phenylbis(hydroxymethyl)phosphine sulfide (PHPS) with acetals and ketals. /sup 31/P NMR Spectra were recorded at 10.2 HMz on a KGU-4 spectrometer with proton noise decoupling at 25.2 MHz. Chemical shifts are given relative to 85% H/sub 3/PO/sub 4/ (negative values to higher field). PMR Spectra were measured on a Varian T60 machine at 34.5/sup 0/C. Treatment of phenylbis(hydroxymethyl)phosphine sulfide with acetals and ketals gives the corresponding 2-substituted and 2,2-disubstituted 5-phenyl-5-thio-1,3,5-dioxaphosphorinanes in which the P-Phenyl substituent occupies an axial position.
- Research Organization:
- A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan, USSR
- OSTI ID:
- 5737043
- Journal Information:
- Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 36:2; ISSN BACCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ALDEHYDES
CHALCOGENIDES
CHEMICAL REACTIONS
CHEMICAL SHIFT
COUPLING
COUPLING CONSTANTS
HETEROCYCLIC COMPOUNDS
HYDROGEN 1
HYDROGEN ISOTOPES
HYPERFINE STRUCTURE
INTERMEDIATE COUPLING
ISOMERIZATION
ISOMERS
ISOTOPES
J-J COUPLING
LIGHT NUCLEI
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PHOSPHINES
PHOSPHORUS 31
PHOSPHORUS COMPOUNDS
PHOSPHORUS ISOTOPES
SPECTRA
STABLE ISOTOPES
STEREOCHEMISTRY
SULFIDES
SULFUR COMPOUNDS
SYNTHESIS
THIOLS
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ALDEHYDES
CHALCOGENIDES
CHEMICAL REACTIONS
CHEMICAL SHIFT
COUPLING
COUPLING CONSTANTS
HETEROCYCLIC COMPOUNDS
HYDROGEN 1
HYDROGEN ISOTOPES
HYPERFINE STRUCTURE
INTERMEDIATE COUPLING
ISOMERIZATION
ISOMERS
ISOTOPES
J-J COUPLING
LIGHT NUCLEI
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PHOSPHINES
PHOSPHORUS 31
PHOSPHORUS COMPOUNDS
PHOSPHORUS ISOTOPES
SPECTRA
STABLE ISOTOPES
STEREOCHEMISTRY
SULFIDES
SULFUR COMPOUNDS
SYNTHESIS
THIOLS