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A high-resolution study of Si, P, S, Cl, and Ar LMM Auger electrons produced by 0. 4 to 2. 0 MeV proton bombardment

Thesis/Dissertation ·
OSTI ID:5732465
Gaseous targets of SiH{sub 4}, PH{sub 3}, SO{sub 2}, Ch{sub 3}Cl, and Ar have been bombarded by 0.4 to 2.0 MeV protons to produce LMM Auger yields of Si, P, S, Cl and Ar at 0.45 eV resolution. The LMM Auger electrons were then transmitted in a constant energy mode and detected by means of a spherical spectrometer positioned at an angle of 90 to the primary proton beam direction. From the measured Auger yields, the L-shell ionization cross sections for the elements Si, P, S, Cl, and Ar have been obtained. The L-shell ionization cross sections obtained thereby are compared to existing experimental L-shell ionization cross sections and also to various theoretical predictions. Also, the LMM Auger spectra in gaseous SiH{sub 4}, SO{sub 2}, CH{sub 3}Cl and Ar excited by 1.4 MeV H{sub 2}{sup +} ion bombardment and for PH{sub 3} under 0.7 MeV H{sub 2}{sup +} ion bombardment at 0.3 eV resolution have been measured. With the exception of SO{sub 2}, all the other spectra have been decomposed into several lines using Gaussian curve-fitting methods. The measured line energies, line widths, and line intensities in the various spectra are presented. The line energies in the SiH{sub 4} spectrum measured are compared to experimental energies obtained elsewhere and with existing theoretical predictions. Also for Ph{sub 3} and Ch{sub 3}Cl, the line energies measured are compared to calculated Auger energies using a simple model approach. Possible final Auger transitions have been assigned.
Research Organization:
Baylor Univ., Waco, TX (United States)
OSTI ID:
5732465
Country of Publication:
United States
Language:
English