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Nitrification enhancement by powdered activated carbon addition in activated sludge

Thesis/Dissertation ·
OSTI ID:5717801
Previous investigators provided evidence that the addition of powdered activated carbon (PAC) to nitrifying activated sludge (AS) can improve nitrification rates. Plausible but unsubstantiated mechanisms proposed to explain these observations include adsorption of compounds toxic to nitrifiers; enhanced growth of nitrifiers and/or concentration of trace nutrients on the carbon surface. The major objective of this research is to further define the mechanics of nitrification enhancement in PAC-AS. Using refinery and synthetic wastewater feed, a series of acute and chronic experiments, as well as experiments with variable carbon dosages, was conducted to evaluate the relative importance of adsorption, suspended solids, and microbial acclimation on AS nitrification rates. The general procedure was to compare the effect of a spiked adsorbable/non-adsorbable, inhibitory compound on nitrification rates in AS and in AS supplemented either with PAC or inert suspended solids (bentonite clay). With spiked adsorbable inhibitors, the acute experiments demonstrated nitrification enhancement due to PAC addition in unacclimated sludge cultures. Statistically significant enhancement due to either PAC or bentonite addition was not evident in any experiment where a nonadsorbable inhibitor was added. A chronic experiment gave evidence that the addition of PAC of AS can inhibit nitrification by virtue of desorption of a previously adsorbed inhibitor. In this same experiment, it was shown that an adequate dose of virgin PAC can dramatically arrest the effect of an adsorbable inhibitor and restore full nitrification capability.
Research Organization:
California Univ., Los Angeles (USA)
OSTI ID:
5717801
Country of Publication:
United States
Language:
English