Hydrogen trajectories in alkene to carbene rearrangements. Unequal deuterium isotope effects for the axial and equatorial paths
Journal Article
·
· Journal of the American Chemical Society
- Johns Hopkins Univ., Baltimore, MD (United States)
- Univ. of Maryland, Baltimore, MD (United States)
The rearrangement of alkenes to carbenes yields deuterium isotope effects upon irradiation for the axial and equatorial paths. This study has focused on the migration trajectory that accompanies the rearrangement. 15 refs.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 569233
- Journal Information:
- Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 23 Vol. 114; ISSN JACSAT; ISSN 0002-7863
- Country of Publication:
- United States
- Language:
- English
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