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Oxides of the type TlSr sub 2 Cu sub 1 minus x M sub x O sub 5 (M=Fe, Co) having the 121 structure

Journal Article · · Journal of Solid State Chemistry; (USA)
OSTI ID:5684208
;  [1];  [2]
  1. E. I. duPont de Nemours and Co., Wilmington, Delaware (USA)
  2. Los Alamos National Lab., New Mexico (USA)
Oxides of the type TlSr{sub 2}Cu{sub 1{minus}x}M{sub x}O{sub 5}(M = Fe, 0.5{le}x{le}0.75; M = Co, 0.3 {le}x{le} 0.5) have been synthesized and characterized for the first time. These oxides were monophasic and crystallized in a primitive tetragonal structure (c-parameters{approximately} 9.0 {angstrom}). Lattice parameters vary systematically with x. All the oxides show semiconducting behavior. Neutron powder diffraction study on TlSr{sub 2}Cu{sub 0.4}Fe{sub 0.6}O{sub 5{minus}{delta}} shows structural features similar to those of other 121 oxides, but has comparatively less disorder in the Tl-O plane and has axially compressed Cu/Fe-O{sub 6} octahedra.
OSTI ID:
5684208
Journal Information:
Journal of Solid State Chemistry; (USA), Journal Name: Journal of Solid State Chemistry; (USA) Vol. 91:2; ISSN 0022-4596; ISSN JSSCB
Country of Publication:
United States
Language:
English

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