Paths of conversion of intermediate metal-hydroperoxide complex in the process of catalyzed decomposition of hydroperoxide with the participation of a copper chelate

Journal Article · Mon Jul 01 00:00:00 EDT 1985 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF01157322· OSTI ID:5658453

Gagarina, A B; Rubailo, V L; Smurova, L A

The authors obtain quantitative characteristics of the decomposition of cyclohexenyl hydroperoxide ROOH (I) with the participation of a copper chelate as a catalyst. In the elementary stages of free radical formation in the process of hydroperoxide decomposition catalyzed by a copper chelate, there is no change in the ligand environment of the original catalyst. The interaction of the hydroperoxide complex of copper with the free radicals is the basic process leading to changes in the ligand environment of the original catalyst.

• Research Organization: Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow
• OSTI ID: 5658453
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 34:1, PT. 1; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ABSORPTION SPECTRA
CATALYSIS
CATALYTIC EFFECTS
CHELATES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COMPLEXES
COPPER COMPLEXES
HYDROCARBONS
KINETICS
LIGANDS
ORGANIC COMPOUNDS
OXIDATION
OXYGEN COMPOUNDS
PEROXIDES
RADICALS
REACTION INTERMEDIATES
REACTION KINETICS
SPECTRA
SPECTROPHOTOMETRY
TRANSITION ELEMENT COMPLEXES