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Analysis of the series of moderately heavy fermion materials: CeSn/sub 3/, USn/sub 3/, and NpSn/sub 3/

Conference ·
OSTI ID:5652325
The materials CeSn/sub 3/, USn/sub 3/, and NpSn/sub 3/ are all moderately heavy Fermion compounds with electronic specific heat coefficients of 73, 169, and 242 mJ/mole K/sup 2/. CeSn/sub 3/ is known as a mixed valent system and NpSn/sub 3/ is a weak itinerant antiferromagnet. All three are strongly enhanced. Being in the relatively simple Au/sub 3/Cu structure, they form an excellent set of materials to study as representatives of strongly enhanced systems. One would like to ascertain what properties can be determined from band calculations based on density functional theory in the local density approximation. It has already been shown that the Fermi surface topology of CeSn/sub 3/ can be well described in this way even though the experimental masses are much larger than the band results. The enhancement factor for USn/sub 3/ is even larger and NpSN/sub 3/ is indeed predicted to go magnetic. We present here fully relativistic SCF calculations for these materials and discuss the relation between our results and what is known experimentally.
Research Organization:
Argonne National Lab., IL (USA)
DOE Contract Number:
W-31109-ENG-38
OSTI ID:
5652325
Report Number(s):
CONF-8505138-12; ON: DE85014973
Country of Publication:
United States
Language:
English