Crystal and molecular structure of [CpRu(PPh[sub 3])[sub 2](t[minus]C[sub 4]H[sub 4]SH)]BF[sub 4]
Journal Article
·
· Journal of Crystallographic and Spectroscopic Research; (United States)
- Arkansas State Univ., State University, AR (United States)
- Univ. of Arkansas, Fayetteville, AR (United States)
The structure of the [CpRu(PPh[sub 3])[sub 2](t[minus]C[sub 4]H[sub 4]SH)]BF[sub 4] complex was determined by X-ray diffraction techniques; monoclinic space group P2[sub 1]/c, a = 14.662(9), b = 18.515(7), c = 15.368(6) [angstrom], [beta] = 101.88(5)[degrees], V = 4082(6) [angstrom][sup 3], Z = 4, R = 0.049, R[sub w] = 0.057. The Ru is attached to two triphenylphosphine ligands, a cyclopentadienyl and the t-butylmercaptan. The Ru-S distance is 2.396(2)[angstrom] and the S-H distance is 1.289(2)[angstrom].
- OSTI ID:
- 5650354
- Journal Information:
- Journal of Crystallographic and Spectroscopic Research; (United States), Journal Name: Journal of Crystallographic and Spectroscopic Research; (United States) Vol. 23:8; ISSN JCREDB; ISSN 0277-8068
- Country of Publication:
- United States
- Language:
- English
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Journal Article
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Wed Mar 31 23:00:00 EST 1993
· Journal of Crystallographic and Spectroscopic Research; (United States)
·
OSTI ID:6443590
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Journal Article
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Wed May 13 00:00:00 EDT 1992
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·
OSTI ID:6975972
Synthesis, structure, and reactivity of (. eta. sup 4 (5e)-butadienyl)ruthenium complexes: Crystal structures of CpRu = C(Ph)-. eta. sup 3 -(C(Ph)C(Ph)CH(Ph)), CpRuC(Ph) = C(Ph)-. eta. sup 2 -(C(Ph) = CH(Ph))P(OMe) sub 3 , and CpRu sub 2 (. mu. -(Z)-C(Ph) = CH(Ph))(CO) sub 2 (. eta. sup 4 -C sub 4 Ph sub 4 )
Journal Article
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Tue May 01 00:00:00 EDT 1990
· Organometallics; (USA)
·
OSTI ID:6429153
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
COHERENT SCATTERING
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DIFFRACTION
LATTICE PARAMETERS
MOLECULAR STRUCTURE
MONOCLINIC LATTICES
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PHOSPHINES
PHOSPHORUS COMPOUNDS
REFRACTORY METAL COMPOUNDS
RUTHENIUM COMPOUNDS
SCATTERING
THIOLS
TRANSITION ELEMENT COMPOUNDS
X-RAY DIFFRACTION
400201* -- Chemical & Physicochemical Properties
COHERENT SCATTERING
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DIFFRACTION
LATTICE PARAMETERS
MOLECULAR STRUCTURE
MONOCLINIC LATTICES
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PHOSPHINES
PHOSPHORUS COMPOUNDS
REFRACTORY METAL COMPOUNDS
RUTHENIUM COMPOUNDS
SCATTERING
THIOLS
TRANSITION ELEMENT COMPOUNDS
X-RAY DIFFRACTION