Mechanistic studies related to the metal catalyzed reduction of carbon monoxide to hydrocarbons. Progress report, April 1, 1980-January 31, 1982. [Crystal structures of metal formyl and acetyl compounds N (CH/sub 2/CH/sub 3/)/sub 4//sup +/ (CO)/sub 3/((C/sub 6/H/sub 5/O)/sub 3/P)FeCOR/sup -/ were R = H, CH/sub 3/]

Technical Report · Fri Jan 01 04:00:00 EST 1982

OSTI ID:5647874

Casey, C P

The crystal structures of analogous metal formyl and metal acetyl complexes have been determined and the differences analyzed. New heterobimetallic compounds have been prepared for study as possible carbon monoxide hydrogenation catalysts. The synthesis of related bridging methyl, methylene, and methylidyne complexes has been achieved. Several new types of reversible chemical reactions have been discovered including eta/sup 5/-C/sub 5/H/sub 5/ yields eta/sup 1/-C/sub 5/H/sub 5/ rearrangements and addition of C-H bonds to alkenes.

• Research Organization: Wisconsin Univ., Madison (USA)
• DOE Contract Number: AS02-77ER04222
• OSTI ID: 5647874
• Report Number(s): DOE/ER/04222-4; ON: DE82009796
• Country of Publication: United States
• Language: English

Related Subjects

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010404* -- Coal
Lignite
& Peat-- Gasification
090121 -- Hydrocarbon Fuels-- Chemical Synthesis-- (1976-1989)
10 SYNTHETIC FUELS
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ACETYL RADICALS
ACYL RADICALS
ARSENIC COMPOUNDS
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CATALYSTS
CHALCOGENIDES
CHEMICAL REACTIONS
COBALT COMPLEXES
COMPLEXES
CRYSTAL STRUCTURE
FORMYL RADICALS
IRON COMPLEXES
MANGANESE COMPLEXES
METHANATION
ORGANIC ARSENIC COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
RADICALS
REACTION INTERMEDIATES
REDUCTION
RESEARCH PROGRAMS
RHENIUM COMPLEXES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES