Mechanistic studies related to the metal catalyzed reduction of carbon monoxide to hydrocarbons. Final report, April 1, 1977-June 30, 1985
Technical Report
·
OSTI ID:5334708
Studies of compounds related to proposed intermediates in the hydrogenation of carbon monoxide over homogeneous and heterogeneous catalysts have been carried out. The synthesis, structure, and reactions of metal formyl compounds have been investigated. The synthesis and desproportionation reactions of hydroxymethyl metal compounds have been explored. Reactions involving interconversion of n/sup 5/- and n'-C/sub 5/H/sub 5/ organometallic compounds have been discovered. New synthetic routes to bimetallic compounds with bridging hydrocarbon ligands have been developed. The first bimetallic compound with a budging CH ligand has been prepared. The hydrocarbation reaction in which the CH bond of a bridging methylidyne complex adds across a carbon-carbon double bond has been discovered. New heterobimetallic compounds linked by a heterodifunctional ligand and heterobimetallic compounds with directly bonded early and late transition metals have been synthesized in a search for new CO hydrogenation catalysts. 36 refs.
- Research Organization:
- Wisconsin Univ., Madison (USA)
- DOE Contract Number:
- AC02-77ER04222
- OSTI ID:
- 5334708
- Report Number(s):
- DOE/ER/04222-6; ON: DE85017049
- Country of Publication:
- United States
- Language:
- English
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Mechanistic studies related to the metal catalyzed reduction of carbon monoxide to hydrocarbons. Final report, April 1, 1977-June 30, 1984
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Mechanistic studies related to the metal catalyzed reduction of carbon monoxide to hydrocarbons. Progress report, April 1, 1979-March 31, 1980
Technical Report
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Tue Jan 31 23:00:00 EST 1984
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Mechanistic studies related to the metal catalyzed reduction of carbon monoxide to hydrocarbons. Progress report, April 1, 1980-January 31, 1982. [Crystal structures of metal formyl and acetyl compounds N (CH/sub 2/CH/sub 3/)/sub 4//sup +/ (CO)/sub 3/((C/sub 6/H/sub 5/O)/sub 3/P)FeCOR/sup -/ were R = H, CH/sub 3/]
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Mechanistic studies related to the metal catalyzed reduction of carbon monoxide to hydrocarbons. Progress report, April 1, 1979-March 31, 1980
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Related Subjects
090121 -- Hydrocarbon Fuels-- Chemical Synthesis-- (1976-1989)
10 SYNTHETIC FUELS
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ACETYL RADICALS
ACYL RADICALS
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CATALYSIS
CHALCOGENIDES
CHEMICAL PREPARATION
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
FORMYL RADICALS
HYDROCARBONS
HYDROGENATION
KINETICS
LIGANDS
METHANATION
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
RADICALS
REACTION INTERMEDIATES
REACTION KINETICS
REDUCTION
SYNTHESIS
10 SYNTHETIC FUELS
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ACETYL RADICALS
ACYL RADICALS
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CATALYSIS
CHALCOGENIDES
CHEMICAL PREPARATION
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
FORMYL RADICALS
HYDROCARBONS
HYDROGENATION
KINETICS
LIGANDS
METHANATION
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
RADICALS
REACTION INTERMEDIATES
REACTION KINETICS
REDUCTION
SYNTHESIS