Spectra of electron-beam pumped XeF lasers
An analysis is presented of the lasing spectrum of the rovibronic XeF(B--X) transition as observed in an electron-beam pumped laser. The intricate spin--split rotational and vibrational structure in the 351- and 353-nm lasing emission is investigated, and insight is gained on the processes responsible for the vibrational, rotational, and spin inhomogeneities manifested in the spectra. Explanations of the data are developed in terms of near-resonant vibration--rotation transfer, rotational relaxation rate differences in the B and X states, rapid dissociation of the rotational resonances near the dissociation limit of the ground state, relatively slow collisional spin relaxation, and optical coupling of spin states. The implications for narrow band excitation in the 351- and 353-nm bands are noted. The rotational relaxation rates of the X and B states of XeF are estimated in the Appendix.
- Research Organization:
- Rockwell International, Rocketdyne Division, 6633 Canoga Avenue, Canoga Park, California 91303
- OSTI ID:
- 5612704
- Journal Information:
- Appl. Opt.; (United States), Journal Name: Appl. Opt.; (United States) Vol. 27:1; ISSN APOPA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
420300* -- Engineering-- Lasers-- (-1989)
ANGULAR MOMENTUM
ELECTRICAL PUMPING
ELECTRON BEAM PUMPING
EMISSION
ENERGY LEVELS
ENERGY-LEVEL TRANSITIONS
EXCIMER LASERS
EXCITED STATES
FLUORIDES
FLUORINE COMPOUNDS
GAS LASERS
HALIDES
HALOGEN COMPOUNDS
LASERS
PARTICLE PROPERTIES
PUMPING
RARE GAS COMPOUNDS
ROTATIONAL STATES
SPECTRA
SPIN
STIMULATED EMISSION
ULTRAVIOLET SPECTRA
VIBRATIONAL STATES
XENON COMPOUNDS
XENON FLUORIDES