Synthesis, characterization and reactivity of early transition metal neo-pentoxides
Conference
·
OSTI ID:560224
- Sandia National Labs., Albuquerque, NM (United States)
Titanium neo-pentoxide was isolated by the alcoholysis exchange between Ti(OCHMe{sub 2}){sub 4} and ONep. The molecule, [Ti(ONep){sub 4}]{sub 2}, was characterized using X-ray analysis and solution {sup 17}O, and {sup 47},{sup 49}Ti NMR spectroscopy. This dinuclear complex is the smallest Ti(OR){sub 4} isolated wherein each metal center is 5-coordinated. The molecule is highly soluble in standard solvents and volatile. The reactivity of this compound has been undertaken to compare with the ubiquitous Ti(O-I-Pr){sub 4}. The various compounds isolated and further NMR studies will be reported. Analogous routes to other M(ONep){sub n} will be reported as well.
- Research Organization:
- Sandia National Laboratory
- DOE Contract Number:
- AC04-94AL85000
- OSTI ID:
- 560224
- Report Number(s):
- CONF-970443--
- Country of Publication:
- United States
- Language:
- English
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