(Reactions of metallocumulenes with carbides). Progress report, 1985-1986
Technical Report
·
OSTI ID:5583758
During our first approximately nine months of DOE support, we have begun to investigate several areas of metallacumulene and carbide chemistry. We have continued to develop the alkynylsilane/fluoride method and have found that it is the most reliable procedure for many iron and ruthenium alkynyls ((M) = (Fe(CO)/sub 2/(Cp)), (Ru(PR/sub 3/)/sub 2/(Cp)), etc.). Alkynyl, vinylidene, allenylidene, and butatrienylidene complexes and carbides are studied. 4 figs.
- Research Organization:
- Kentucky Univ., Lexington (USA). Dept. of Chemistry
- DOE Contract Number:
- FG05-85ER13432
- OSTI ID:
- 5583758
- Report Number(s):
- DOE/ER/13432-2; ON: DE86013530
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
CARBIDES
CARBON COMPOUNDS
CHEMICAL PREPARATION
COMPLEXES
CRYSTAL STRUCTURE
LIGANDS
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
RUTHENIUM COMPLEXES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
TUNGSTEN COMPLEXES
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
CARBIDES
CARBON COMPOUNDS
CHEMICAL PREPARATION
COMPLEXES
CRYSTAL STRUCTURE
LIGANDS
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
RUTHENIUM COMPLEXES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
TUNGSTEN COMPLEXES