Metallacumulenes and carbide complexes. Final performance report
We investigated many aspects of transition metal complexes of carbon-rich ligands, including cumulated transition metal carbene complexes of the types vinylidene (M=C=CR{sub 2})(M = Fe, Ru, Os, Mo, W), allenylidene (M=C=C=CR{sub 2}), and butatrienylidene (M=C=C=CR{sub 2}), as well as ``naked`` carbon ligands C{sub 1}, C{sub 2}, and C{sub 3}. In the last 3 years, we began to put some effort into studying the fullerenes. Finally, we investigated initial aspects of the coordination chemistry of thiophenes, from the perspectives of (1) modeling the transition- metal-catalyzed hydrodesulfurization of fossil fuels and (2) development of metal-doped, polythiophene-based polymers.
- Research Organization:
- Kentucky Univ., Lexington, KY (United States). Dept. of Chemistry
- Sponsoring Organization:
- USDOE Office of Energy Research, Washington, DC (United States)
- DOE Contract Number:
- FG05-85ER13432
- OSTI ID:
- 516449
- Report Number(s):
- DOE/ER/13432--T1; ON: DE97009231
- Country of Publication:
- United States
- Language:
- English
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