Halogen-mediated electron transfer between metallocenes of ruthenium and osmium in the oxidation states 4+ and 2+
Journal Article
·
· Inorg. Chem.; (United States)
The rates of self-exchange for several systems of the class MCp/sub 2/X/sup +//Cp/sub 2/, where M is Ru or Os and X is Cl, Br, or I, have been measured by the NMR line-broadening method. For each metal, the rates increase along the halogen series as given above and are more rapid for M = Ru than for the osmium analogues. In consideration of these data, the possibility is raised that these 2e self-exchange reactions and those of other metal ions take place by 1e steps.
- Research Organization:
- Stanford Univ., CA
- OSTI ID:
- 5572202
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 26:17; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
BROMINE
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORINE
COMPLEXES
DATA
DIENES
ELECTRON TRANSFER
ELEMENTS
EXPERIMENTAL DATA
HALOGENS
HYDROCARBONS
INFORMATION
IODINE
KINETICS
MAGNETIC RESONANCE
NMR SPECTRA
NONMETALS
NUCLEAR MAGNETIC RESONANCE
NUMERICAL DATA
ORGANIC COMPOUNDS
OSMIUM COMPLEXES
POLYENES
REACTION KINETICS
RESONANCE
RUTHENIUM COMPLEXES
SPECTRA
TRANSITION ELEMENT COMPLEXES
VALENCE
400201* -- Chemical & Physicochemical Properties
BROMINE
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORINE
COMPLEXES
DATA
DIENES
ELECTRON TRANSFER
ELEMENTS
EXPERIMENTAL DATA
HALOGENS
HYDROCARBONS
INFORMATION
IODINE
KINETICS
MAGNETIC RESONANCE
NMR SPECTRA
NONMETALS
NUCLEAR MAGNETIC RESONANCE
NUMERICAL DATA
ORGANIC COMPOUNDS
OSMIUM COMPLEXES
POLYENES
REACTION KINETICS
RESONANCE
RUTHENIUM COMPLEXES
SPECTRA
TRANSITION ELEMENT COMPLEXES
VALENCE