Association of spin-labeled substrate molecules with poly(sodium 10-undecenoate) and the sodium 10-undecenoate micelle

Journal Article · Wed Nov 18 04:00:00 EST 1981 · J. Am. Chem. Soc.; (United States)

DOI:https://doi.org/10.1021/ja00413a002· OSTI ID:5535827

Sprague, E D; Duecker, D C; Larrabee, Jr, C E

Poly(sodium 10-undecenoate) is intuitively expected to have some of the characteristics of micelles in aqueous solution. Its ability to associate with substrate molecules has been tested with spin-labeled probes. Electron spin resonance (ESR) measurements show unambiguously that the polymer readily associates with both amphiphilic and hydrophobic substrates, as does the sodium 10-undecenoate micelle. Analysis of the ESR spectra allows a comparison of the associated species formed in polymer solution with those formed in micelle solution. Both similarities and differences are observed. 24 references.

• OSTI ID: 5535827
• Journal Information: J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 103:23; ISSN JACSA
• Country of Publication: United States
• Language: English

Related Subjects

02 PETROLEUM
020300* -- Petroleum-- Drilling & Production
AGGLOMERATION
COMPARATIVE EVALUATIONS
DISPLACEMENT FLUIDS
ELECTRON SPIN RESONANCE
FLUIDS
KINETICS
MAGNETIC RESONANCE
MICELLAR SYSTEMS
POLYMERS
REACTION KINETICS
RESONANCE
SYNTHESIS