Hexaaza macrocyclic complexes of the lanthanides
Journal Article
·
· Inorg. Chem.; (United States)
The authors systematically investigate the conditions leading to the metal-templated macrocyclic synthesis and obtain by an appropriate combination of counterions and experimental conditions, two series of complexes of the macrocyclic ligand L = C/sub 22/H/sub 26/N/sub 6/, with every lanthanide(III) ion except radioactive Pm. Their synthesis, characterization, and properties are described here. 13 references, 2 figures.
- Research Organization:
- Virginia Commonwealth Univ., Richmond
- OSTI ID:
- 5496726
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 25:10; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
400702* -- Radiochemistry & Nuclear Chemistry-- Properties of Radioactive Materials
ABSORPTION SPECTROSCOPY
CHEMICAL ANALYSIS
CHEMICAL PREPARATION
CHEMICAL PROPERTIES
COMPLEXES
DATA
EXPERIMENTAL DATA
GRAVIMETRIC ANALYSIS
INFORMATION
MAGNETIC RESONANCE
NUCLEAR MAGNETIC RESONANCE
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
QUANTITATIVE CHEMICAL ANALYSIS
RARE EARTH COMPLEXES
RESONANCE
SPECTROSCOPY
SYNTHESIS
THERMAL ANALYSIS
THERMAL GRAVIMETRIC ANALYSIS
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
400702* -- Radiochemistry & Nuclear Chemistry-- Properties of Radioactive Materials
ABSORPTION SPECTROSCOPY
CHEMICAL ANALYSIS
CHEMICAL PREPARATION
CHEMICAL PROPERTIES
COMPLEXES
DATA
EXPERIMENTAL DATA
GRAVIMETRIC ANALYSIS
INFORMATION
MAGNETIC RESONANCE
NUCLEAR MAGNETIC RESONANCE
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
QUANTITATIVE CHEMICAL ANALYSIS
RARE EARTH COMPLEXES
RESONANCE
SPECTROSCOPY
SYNTHESIS
THERMAL ANALYSIS
THERMAL GRAVIMETRIC ANALYSIS